Amphidinolide G
Products Class: Other natural seafood products
Content: 5%,10%,15%,20% Amphidinolide G
Detection Method: UV
Molecular formula: C32H50 O8
Relative molecular mass: 563
Character: brown powder
Origin: dinoflagellate Aphidinium sp.
Apologies for the abridgement of blogging – turns out this writing-the-thesis affair is absolutely time consuming. Feel chargeless to allocution amidst yourselves… Anyway, accustomed account has been resumed for today, with addition Amphidinolide in the bag (actually a brace – Amphidinolide H & G). As with a lot of macrolide syntheses, there’s affluence of leg-work to get the bits together, and a amount of acquaintance due to the blazon of allure acclimated to accomplish ‘em.
Absolute stereochemistry of Amphidinolide G (1) and H (2), almighty cytotoxic 27- and 26-membered macrolides, respectively, abandoned from a abyssal dinoflagellate Amphidinium sp., was bent by X-ray diffraction analysis, amalgam of a abasement artefact (3) of 2, and interconversion amid 1 and 2.
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