Sunday, April 1, 2012

How to1 get 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3)?

CAS:96556-05-7
Molecular Formula:C9H21N3
Molecular Weight: 171.28g/mol
Description
1,4,7-Trimethyl-1,4,7-triazacyclononane is useful ligand for preparing transition metal complexes (1,2,3).
1,4,7-Triazacyclononane, known as "TACN" which is pronounced "tack-en," is a cyclic organic compound with the formula C6H12(NH)3. TACN is derived, formally speaking, from cyclononane by replacing three equidistant CH2 groups with NH groups. TACN is one of the oligomers derived from aziridine, C2H4NH. Other members of the series include piperazine, C4H8(NH)2, and the cyclic tetramer 1,4,7,10-tetraazacyclododecane.
TACN is a popular tridentate ligand. It is threefold symmetric and binds to one face of an octahedron of metalloids and transition metals. The (TACN)M unit is kinetically inert, allowing further synthetic transformations on the other coordination sites.
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