Pyranine is a hydrophilic, pH-sensitive fluorescent dye from the group of chemicals known as arylsulfonates. Pyranine is soluble in water and has applications as a coloring agent, biological stain, optical detecting reagent, and a pH indicator. One example would be the measurement of intracellular pH. Pyranine is also found in highlighters and soaps
APPLICATIONS of Pyranine
Solvent dyes are insoluble in water but soluble in nonpolar organic solvents and fats. It is usually used as a solution in an organic solvent. Azo structure solvent dyes are often responsible yellow-red color whereas anthraquinone structure solvent dyes tend to be green-blue. Some other structures for solvent dyes include heterocyclic rings, metal complex, pyrazolone, xanthene, and ketoamine. Solvent dyes do not ionise. Solvent dye, undergoing molecular rearrangement, is dissoluted in the substrate. It colours and binds to the lipids resulting in showing colored regions. In industrial field, it is used in coloring oils, waxes, greases, fats, hydrocarbons derivatives, polishes, oily insecticides, and acrylic emulsions. Pyranine (sulfonated hydroxy pyrene trisodium salt) is soluble in water and has applications in the field of :
Coloring agent for drug and cosmetics
Biological stain
Optical detecting reagent for bile acids
Flash-lamp laser dye
pH indicator for physiological range
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Wednesday, February 29, 2012
Tuesday, February 28, 2012
What is Silicon dioxide used for?
Silicon dioxide, also known as silica (from the Latin silex), is an oxide of silicon with the chemical formula SiO2. It has been known for its hardness since antiquity. Silica is most commonly found in nature as sand or quartz, as well as in the cell walls of diatoms.[2][3]
Silicon dioxide is manufactured in several forms including fused quartz, crystal, fumed silica (or pyrogenic silica, trademarked Aerosil or Cab-O-Sil), colloidal silica, silica gel, and aerogel.
Silicon dioxide is used primarily in the production of glass for windows, drinking glasses, beverage bottles, and many other uses. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many whiteware ceramics such as earthenware, stoneware, porcelain, as well as industrial Portland cement.
Silicon dioxide is a common additive in the production of foods, where it is used primarily as a flow agent in powdered foods, or to absorb water in hygroscopic applications. It is the primary component of diatomaceous earth which has many uses ranging from filtration to insect control. It is also the primary component of rice husk ash which is used, for example, in filtration and cement manufacturing.
Silicon dioxide is formed when silicon is exposed to oxygen (or air). A very shallow layer (approximately 1 nm or 10 Å) of so-called native oxide is formed on the surface when silicon is exposed to air under ambient conditions. Higher temperatures and alternative environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures between 600 and 1200 °C, using so-called dry or wet oxidation with O2 or H2O, respectively. The depth of the layer of silicon replaced by the dioxide is 44% of the depth of the silicon dioxide layer produced.
Health effects
Inhaling finely divided crystalline silica dust in very small quantities (OSHA allows 0.1 mg/m3) over time can lead to silicosis, bronchitis, or cancer, as the dust becomes lodged in the lungs and continuously irritates them, reducing lung capacities. (In the body crystalline silica particles do not dissolve over clinically relevant periods of time.) This effect can create an occupational hazard for people working with sandblasting equipment, products that contain powdered crystalline silica and so on. Children, asthmatics of any age, allergy sufferers, and the elderly (all of whom have reduced lung capacity) can be affected in much less time. Amorphous silica, such as fumed silica is not associated with development of silicosis, but may cause irreversible lung damage in some cases. Laws restricting silica exposure with respect to the silicosis hazard specify that they are concerned only with silica that is both crystalline and dust-forming.
Note however, that plant materials with high silica phytolith content, appear to be of importance to grazing animals, from chewing insects to ungulates. It is known that it accelerates tooth wear at least, and has been doing so for hundreds of millions of years.
A study which followed subjects for 15 years found that higher levels of silica in water appeared to decrease the risk of dementia. The study found that with an increase of 10 milligram-per-day of the intake of silica in drinking water, the risk of dementia dropped by 11%.
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Silicon dioxide is manufactured in several forms including fused quartz, crystal, fumed silica (or pyrogenic silica, trademarked Aerosil or Cab-O-Sil), colloidal silica, silica gel, and aerogel.
Silicon dioxide is used primarily in the production of glass for windows, drinking glasses, beverage bottles, and many other uses. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many whiteware ceramics such as earthenware, stoneware, porcelain, as well as industrial Portland cement.
Silicon dioxide is a common additive in the production of foods, where it is used primarily as a flow agent in powdered foods, or to absorb water in hygroscopic applications. It is the primary component of diatomaceous earth which has many uses ranging from filtration to insect control. It is also the primary component of rice husk ash which is used, for example, in filtration and cement manufacturing.
Silicon dioxide is formed when silicon is exposed to oxygen (or air). A very shallow layer (approximately 1 nm or 10 Å) of so-called native oxide is formed on the surface when silicon is exposed to air under ambient conditions. Higher temperatures and alternative environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures between 600 and 1200 °C, using so-called dry or wet oxidation with O2 or H2O, respectively. The depth of the layer of silicon replaced by the dioxide is 44% of the depth of the silicon dioxide layer produced.
Health effects
Inhaling finely divided crystalline silica dust in very small quantities (OSHA allows 0.1 mg/m3) over time can lead to silicosis, bronchitis, or cancer, as the dust becomes lodged in the lungs and continuously irritates them, reducing lung capacities. (In the body crystalline silica particles do not dissolve over clinically relevant periods of time.) This effect can create an occupational hazard for people working with sandblasting equipment, products that contain powdered crystalline silica and so on. Children, asthmatics of any age, allergy sufferers, and the elderly (all of whom have reduced lung capacity) can be affected in much less time. Amorphous silica, such as fumed silica is not associated with development of silicosis, but may cause irreversible lung damage in some cases. Laws restricting silica exposure with respect to the silicosis hazard specify that they are concerned only with silica that is both crystalline and dust-forming.
Note however, that plant materials with high silica phytolith content, appear to be of importance to grazing animals, from chewing insects to ungulates. It is known that it accelerates tooth wear at least, and has been doing so for hundreds of millions of years.
A study which followed subjects for 15 years found that higher levels of silica in water appeared to decrease the risk of dementia. The study found that with an increase of 10 milligram-per-day of the intake of silica in drinking water, the risk of dementia dropped by 11%.
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Monday, February 27, 2012
What is Crystal Violet Lactone?
Crystal Violet Lactone (CVL) is a leuco dye, a lactone derivate of crystal violet 10B. In pure state it is a slightly yellowish crystalline powder, soluble in nonpolar or slightly polar organic solvents.
The central carbon in the leuco form is in a tetraedric configuration, forming four covalent bonds. In acidic environment the lactone ring is broken, the central carbon loses one valence and becomes a resonance stabilized carbocation (although it might be better to draw the resonance structure with the cation on nitrogen), this planar carbon interconnecting the π systems of the aromatic rings and the amino functional groups to form one large conjugated system acting as a chromophore with strong absorption in visible spectrum, giving this compound its distinctive color.
Crystal Violet Lactone was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, e.g. in the Hypercolor line of clothing. One of its novel uses is a security marker for fuels.
It may cause allergic contact dermatitis in people handling the carbonless copy paper.
Crystal Violet Lactone occurs as blue-green crystals or pale green powder with its melting point 180-183°C. It is soluble in nonpolar or slightly polar organic solvents,insoluble in water.Crystal violet lactone may be sensitive to excessive light and heat. Crystal violet lactone (CVL) is a leuco dye, a lactone derivate of crystal violet 10B.It was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, eg. in the Hypercolor line of clothing. One of its novel uses is a security marker for fuels.
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The central carbon in the leuco form is in a tetraedric configuration, forming four covalent bonds. In acidic environment the lactone ring is broken, the central carbon loses one valence and becomes a resonance stabilized carbocation (although it might be better to draw the resonance structure with the cation on nitrogen), this planar carbon interconnecting the π systems of the aromatic rings and the amino functional groups to form one large conjugated system acting as a chromophore with strong absorption in visible spectrum, giving this compound its distinctive color.
Crystal Violet Lactone was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, e.g. in the Hypercolor line of clothing. One of its novel uses is a security marker for fuels.
It may cause allergic contact dermatitis in people handling the carbonless copy paper.
Crystal Violet Lactone occurs as blue-green crystals or pale green powder with its melting point 180-183°C. It is soluble in nonpolar or slightly polar organic solvents,insoluble in water.Crystal violet lactone may be sensitive to excessive light and heat. Crystal violet lactone (CVL) is a leuco dye, a lactone derivate of crystal violet 10B.It was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, eg. in the Hypercolor line of clothing. One of its novel uses is a security marker for fuels.
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How to get 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin?
CAS Number: 25440-14-6
Molecular Weight: 974.56
Molecular Formula: C44H10F20N4
grade purum
assay ≥98.0% (HPLC)
Description
Electron-deficient porphyrin; preparation of metal complexes in DMF under argon.
5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin iron(III) chloride complex is generally immediately available in most volumes.
5,10,15,20-tetrakis(pentafluorophenyl)porphyrin reacts with a range of nucleophiles (amines, alcohols, thiols, nitrogen heterocycles, and others) resulting in the nucleophilic aromatic substitution of the para-F atoms of the pentafluorophenyl groups. This reaction, which was fortuitously discovered by Kadish and collaborators in 1990, is now being extensively used to synthesize porphyrins bearing electron-donating substituents in the para-position of their meso-aryl groups. This mini-review highlights the methods of synthesis of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, the use of its metal complexes in catalysis and its reaction with nucleophiles to yield new monomeric porphyrins, porphyrins supported in polymers or new polymeric porphyrin matrices useful for heterogeneous catalysis.
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Molecular Weight: 974.56
Molecular Formula: C44H10F20N4
grade purum
assay ≥98.0% (HPLC)
Description
Electron-deficient porphyrin; preparation of metal complexes in DMF under argon.
5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin iron(III) chloride complex is generally immediately available in most volumes.
5,10,15,20-tetrakis(pentafluorophenyl)porphyrin reacts with a range of nucleophiles (amines, alcohols, thiols, nitrogen heterocycles, and others) resulting in the nucleophilic aromatic substitution of the para-F atoms of the pentafluorophenyl groups. This reaction, which was fortuitously discovered by Kadish and collaborators in 1990, is now being extensively used to synthesize porphyrins bearing electron-donating substituents in the para-position of their meso-aryl groups. This mini-review highlights the methods of synthesis of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, the use of its metal complexes in catalysis and its reaction with nucleophiles to yield new monomeric porphyrins, porphyrins supported in polymers or new polymeric porphyrin matrices useful for heterogeneous catalysis.
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Friday, February 24, 2012
What is Dimethyl Isophthalate?
Dimethyl Isophthalate
Synonyms Dimethyl 1,3-benzenedicarboxylate; Isophthalic acid dimethyl ester
Molecular Formula C10H10O4
Molecular Weight 194.19
CAS Registry Number 1459-93-4
Density 1.1477
Melting point 66-69 ºC
Boiling point 124 ºC (12 mmHg)
Flash point 138 ºC
Water solubility Insoluble
Dimethyl Isophthalate occurs as white to off-white flakes or crystalline powder with its melting point 64-68 °C(lit.) and boiling point 124 °C (12.0016 mmHg) .It is insoluble in water.Dimethyl Isophthalate is used in the production of high molecular weight polyester elastomers.Its purity is not less than 99.0%(GC).It's the grade of EP.The specification is 25G or 500G.
APPLICATIONS
Dimethyl Isophthalate is used in the production of high molecular weight polyester elastomers. Dimethyl Isophthalate strengthen the molecular structure so that finished fibers have the average molecular weight of 20,000 - 30,000. It is used as a modifier of engineering plastics.
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Synonyms Dimethyl 1,3-benzenedicarboxylate; Isophthalic acid dimethyl ester
Molecular Formula C10H10O4
Molecular Weight 194.19
CAS Registry Number 1459-93-4
Density 1.1477
Melting point 66-69 ºC
Boiling point 124 ºC (12 mmHg)
Flash point 138 ºC
Water solubility Insoluble
Dimethyl Isophthalate occurs as white to off-white flakes or crystalline powder with its melting point 64-68 °C(lit.) and boiling point 124 °C (12.0016 mmHg) .It is insoluble in water.Dimethyl Isophthalate is used in the production of high molecular weight polyester elastomers.Its purity is not less than 99.0%(GC).It's the grade of EP.The specification is 25G or 500G.
APPLICATIONS
Dimethyl Isophthalate is used in the production of high molecular weight polyester elastomers. Dimethyl Isophthalate strengthen the molecular structure so that finished fibers have the average molecular weight of 20,000 - 30,000. It is used as a modifier of engineering plastics.
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Wednesday, February 22, 2012
What is Glassy carbon used for?
Glassy carbon, also called vitreous carbon, is a non-graphitizing carbon which combines glassy and ceramic properties with those of graphite. The most important properties are high temperature resistance, hardness (7 Mohs), low density, low electrical resistance, low friction, low thermal resistance, extreme resistance to chemical attack and impermeability to gases and liquids. Glassy carbon is widely used as an electrode material in electrochemistry, as well as for high temperature crucibles and as a component of some prosthetic devices, and can be fabricated as different shapes, sizes and sections.
Glassy carbon electrode (GCE) in aqueous solutions is considered to be an inert electrode for hydronium ion reduction.
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Glassy carbon electrode (GCE) in aqueous solutions is considered to be an inert electrode for hydronium ion reduction.
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Tuesday, February 21, 2012
What is Silicon dioxide?
Silicon dioxide, also known as silica (from the Latin silex), is an oxide of silicon with the chemical formula SiO2. It has been known for its hardness since antiquity. Silica is most commonly found in nature as sand or quartz, as well as in the cell walls of diatoms.
Silica is manufactured in several forms including fused quartz, crystal, fumed silica (or pyrogenic silica, trademarked Aerosil or Cab-O-Sil), colloidal silica, silica gel, and aerogel.
Silica is used primarily in the production of glass for windows, drinking glasses, beverage bottles, and many other uses. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many whiteware ceramics such as earthenware, stoneware, porcelain, as well as industrial Portland cement.
Silicon dioxide is a common additive in the production of foods, where it is used primarily as a flow agent in powdered foods, or to absorb water in hygroscopic applications. It is the primary component of diatomaceous earth which has many uses ranging from filtration to insect control. It is also the primary component of rice husk ash which is used, for example, in filtration and cement manufacturing.
Thin films of silica grown on silicon wafers via thermal oxidation methods can be quite beneficial in microelectronics, where they act as electric insulators with high chemical stability. In electrical applications, it can protect the silicon, store charge, block current, and even act as a controlled pathway to limit current flow.
More about: Silicon dioxide sale
Read more: Chemical synthesis
Silica is manufactured in several forms including fused quartz, crystal, fumed silica (or pyrogenic silica, trademarked Aerosil or Cab-O-Sil), colloidal silica, silica gel, and aerogel.
Silica is used primarily in the production of glass for windows, drinking glasses, beverage bottles, and many other uses. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many whiteware ceramics such as earthenware, stoneware, porcelain, as well as industrial Portland cement.
Silicon dioxide is a common additive in the production of foods, where it is used primarily as a flow agent in powdered foods, or to absorb water in hygroscopic applications. It is the primary component of diatomaceous earth which has many uses ranging from filtration to insect control. It is also the primary component of rice husk ash which is used, for example, in filtration and cement manufacturing.
Thin films of silica grown on silicon wafers via thermal oxidation methods can be quite beneficial in microelectronics, where they act as electric insulators with high chemical stability. In electrical applications, it can protect the silicon, store charge, block current, and even act as a controlled pathway to limit current flow.
More about: Silicon dioxide sale
Read more: Chemical synthesis
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